Guest-induced capsule formation based on concerted interactions in water at neutral pH.
نویسندگان
چکیده
The interaction of a tetracationic calixarene (TAC4) with dianionic guest (BS) in water was studied with NMR, nano-ITC and ESI-MS experiments; the convergent evidence provided by these different techniques shows that the addition of a suitable guest molecule triggers the formation of a homodimeric capsule in aqueous neutral solution.
منابع مشابه
A gemini guest triggers the self-assembly of a calixarene capsule in water at neutral pH.
A gemini guest having both aromatic units and negative charges induces the self-assembling of a homodimeric capsule when interacting with a positively charged calixarene at pH 7.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 38 شماره
صفحات -
تاریخ انتشار 2010